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SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.2. Relevant identified uses of the substance or mixture and uses advised against Preservation of exterior timber surfaces. Applied by brush. See container for details.
Not recommended for interior use on large surface areas or in confined spaces without suitable respiratory protection.
1.3. Details of the supplier of the safety data sheet Crown WoodcareCrown PaintsCrown HouseHollins RoadLancs, BB3 0BGTel: 01254 704951Fax:01254 702678crowntrade.co.uk 2.1. Classification of the substance or mixture Human healthInhalation of organic solvent vapours may be hazardous to health.
Physical and Chemical HazardsFlammable liquid and vapours Naptha (petroleum), hydrotreated heavy - D60 High Flash Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Harmful: may cause lung damage if swallowed.
Repeated exposure may cause skin dryness or cracking.
Vapours may cause drowsiness and dizziness.
Keep away from food, drink and animal feeding stuffs.
Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point.
If swallowed, seek medical advice immediately and show this container or label.
Avoid release to the environment. Refer to special instructions/safety data sheets.
Contains PERMETHRIN. May produce an allergic reaction.
This product does not contain any PBT or vPvB substances.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Naptha (petroleum), hydrotreated heavy - D60 High Flash Aquatic Acute 1 - H400Aquatic Chronic 1 - H410 SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC, <0.1% BENZENE Xn;R65. Xi;R37. N;R51/53.
R66,R67.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition CommentsThe product contains organic solvents. Petroleum substances contained in this product contain less than 0.1% w/w benzene.
General informationIn all cases of doubt, or when symptoms persist, seek medical attention. Never give anything by mouth to an unconscious person.
InhalationRemove to fresh air, keep the patient warm and at rest. If breathing has stopped, administer artificial respiration. Give nothing by mouth. If unconscious, place in a prone position with head to the side (recovery position) and seek medical advice.
IngestionIf accidentally swallowed obtain immediate medical advice. Show this safety data sheet. Keep at rest. Do not induce vomiting. If conscious give milk or water to drink.
Skin contactRemove contaminated clothing. Wash skin thoroughly with soap and water or use a proprietary skin cleaner. Do not use solvents or thinners.
Eye contactContact lenses should be removed. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart, and seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed General informationThe severity of the symptoms described will vary dependant of the concentration and the length of exposure.
Inhalation.
Vapours may cause headache, fatigue, dizziness and nausea.
IngestionMay cause discomfort if swallowed. Nausea, vomiting. Diarrhoea.
Skin contactProlonged contact may cause redness, irritation and dry skin.
Eye contactIrritation of eyes and mucous membranes.
4.3. Indication of any immediate medical attention and special treatment needed Extinguishing mediaExtinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
Unsuitable extinguishing mediaDo not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture Hazardous combustion productsThermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
Unusual Fire & Explosion HazardsNo unusual fire or explosion hazards noted.
Specific hazardsFire creates: Toxic gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Special Fire Fighting ProceduresKeep up-wind to avoid fumes. Cool containers exposed to flames with water until well after the fire is out. Keep run-off water out of sewers and water sources. Dike for water control.
Protective equipment for fire-fightersSelf contained breathing apparatus and full protective clothing must be worn in case of fire.
6.1. Personal precautions, protective equipment and emergency procedures Wear protective clothing as described in Section 8 of this safety data sheet. Ensure suitable personal protection (including respiratory protection) during removal of spillages in a confined area. Take precautionary measures against static discharges. Do not smoke, use open fire or other sources of ignition. Do not breathe vapour. Eye contact MUST be prevented by means of suitable personal protection equipment.
Do not discharge onto the ground or into water courses. Do not allow ANY environmental contamination. Spillages or uncontrolled discharges into watercourses must be IMMEDIATELY alerted to the Environmental Agency or other appropriate regulatory body.
6.3. Methods and material for containment and cleaning up If leakage cannot be stopped, evacuate area. Clean-up personnel should use respiratory and/or liquid contact protection. Wash thoroughly after dealing with a spillage. Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. Absorb spillage with non-combustible, absorbent material. Transfer to a container for disposal. Flush area with plenty of water.
For personal protection, see section 8. For waste disposal, see section 13.
Keep away from heat, sparks and open flame. Eliminate all sources of ignition. Avoid contact with skin and eyes. Static electricity and formation of sparks must be prevented. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Do not eat, drink or smoke when using the product. Observe good chemical hygiene practices. Do not use in confined spaces without adequate ventilation and/or respirator. Provide good ventilation. Container must be kept tightly closed.
7.2. Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Keep containers tightly closed. Keep away from food, drink and animal feeding stuffs. Flammable/combustible - Keep away from oxidisers, heat and flames. Keep in original container. Store away from: Acids. Alkalis.
Storage ClassThe storage of this product is not subject to any statutory requirements.
Usage DescriptionUse product only in accordance with methods listed in section 1.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Naptha (petroleum), hydrotreated heavy - D60 High Ingredient CommentsLT = Long term exposure limit. ST = Short term exposure limit. TWA = Time weighted average. Ppm = Parts per million Mgm-3 = Milligrams per cubic metre. Sk = Indicates a risk of absorption through skin.
Process conditionsProvide eyewash, quick drench.
Engineering measuresProvide adequate ventilation, including appropriate local extraction, to ensure that the defined occupational exposure limit is not exceeded.
Respiratory equipmentIf ventilation is insufficient, suitable respiratory protection must be provided. At work in confined or poorly ventilated spaces, respiratory protection with air supply must be used. Check that mask fits tight and change filter regularly.
Hand protectionProtective gloves must be used if there is a risk of direct contact or splash. Gloves of nitrile rubber, PVA or Viton are recommended.
Eye protectionWear approved chemical safety goggles where eye exposure is reasonably probable.
Other ProtectionWear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
Hygiene measuresWash hands at the end of each work shift and before eating, smoking and using the toilet.
Skin protectionWear apron or protective clothing in case of splashes.
Environmental Exposure ControlsSee section 12.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Initial boiling point and boiling range 180-217Bulk Density There are no known reactivity hazards associated with this product.
Stable under normal temperature conditions and recommended use.
Protect from frost, heat and sunlight.
Materials To AvoidStrong oxidising substances. Strong acids. Strong alkalis.
None at ambient temperatures. Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
11.1. Information on toxicological effects General informationContains small amounts of organic solvents. Extensive use of the product in areas with inadequate ventilation may result in hazardous vapour concentrations.
InhalationWhen working extensively on big surfaces in small and badly ventilated rooms, vapours may develop in concentrations which may cause malaise such as headache, dizziness and nausea.
IngestionNausea, vomiting. Headache. Diarrhoea.
Skin contactMay cause defatting of the skin, but is not an irritant. Repeated exposure may cause skin dryness or cracking. The product contains a small amount of sensitising substance which may provoke an allergic reaction among sensitive individuals after repeated contact.
Eye contactMay cause temporary eye irritation.
Toxicological information on ingredients.
Acute toxicity:Acute Toxicity (Oral LD50)383 mg/kg Rat Acute Toxicity (Dermal LD50)1750 mg/kg Rat 3-IODO-2-PROPYNYLBUTYL CARBAMATE (CAS: 55406-53-6) Acute toxicity:Acute Toxicity (Oral LD50)1470 mg/kg Rat Acute Toxicity (Dermal LD50)> 2000 mg/kg Rabbit Naptha (petroleum), hydrotreated heavy - D60 High Flash (CAS: 64742-48-9) Acute toxicity:Acute Toxicity (Oral LD50)> 5000 mg/kg Rat Acute Toxicity (Dermal LD50)> 2000 mg/kg RabbitAcute Toxicity (Inhalation LC50)> 5000 mg/l (vapours) Rat EcotoxicityDangerous for the environment: May cause long-term adverse effects in the aquatic environment. The product contains a substance which is very toxic to aquatic organisms and which may cause long term adverse effects in the aquatic environment.
Ecological information on ingredients.
Naptha (petroleum), hydrotreated heavy - D60 High Flash (CAS: 64742-48-9) EcotoxicityDangerous for the environment: May cause long-term adverse effects in the aquatic environment.
Do not allow to enter drains, sewers or watercourses.
Ecological information on ingredients.
LC50 96 hours 0.00062 mg/l Onchorhynchus mykiss (Rainbow trout)Acute Toxicity - Aquatic InvertebratesEC50 48 hours 0.0006 mg/l Daphnia magna 3-IODO-2-PROPYNYLBUTYL CARBAMATE (CAS: 55406-53-6) Acute Toxicity - FishLC50 96 hours 0.067 mg/l Onchorhynchus mykiss (Rainbow trout)Acute Toxicity - Aquatic InvertebratesEC50 48 hours 0.16 mg/l Daphnia magnaAcute Toxicity - Aquatic PlantsEC50 72 hours 0.022 mg/l Scenedesmus subspicatus Naptha (petroleum), hydrotreated heavy - D60 High Flash (CAS: 64742-48-9) LC50 96 hours > 1000 mg/l Onchorhynchus mykiss (Rainbow trout)Acute Toxicity - Aquatic InvertebratesEC50 48 hours > 1000 mg/l Daphnia magnaIC 50, 72 Hrs, Algae, mg/l>1000 The product is not expected to be biodegradable.
Bioaccumulative potentialBioaccumulation is unlikely to be significant because of the low water solubility of this product.
This product does not contain any PBT or vPvB substances.
General informationWhen this product, in its liquid state, as supplied or skinned, becomes a waste, it is categorised as hazardous waste, with code 08 01 11 (list of wastes). Part used containers, not drained and/ or rigorously scraped out and containing dried residues of the supplied product, are categorised as non-hazardous waste, with code 08 01 12 (list of wastes). Used containers, drained and/ or rigorously scraped out and containing dried residues of the supplied product, are categorised as non-hazardous waste, with code 15 01 02 or 15 01 04 (list of wastes). If mixed with other wastes, the above waste code may not be applicable.
Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements.
Waste ClassWaste product 08 01 11 Used packaging containg only dried residues 15 01 02 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (3-IODO-2-PROPYNYLBUTYL CARBAMATE ) Class 9: Miscellaneous dangerous substances and articles.
MISCELLANEOUS
DANGEROUS
Environmentally Hazardous Substance/Marine Pollutant 14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Uk Regulatory ReferencesThe products are classified and supplied in accordance with the Chemicals (Hazard Information Packaging for supply) regulations (CHIP). The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. The provision of the Health and Safety at Work Act and the Control of Substances Hazardous to Health regulations apply to the use of this product at work.
Approved Code Of PracticeApproved classification and labelling guide (Sixth edition) The compilation of safety data sheets (Third edition)Guidance NotesWorkplace Exposure Limits EH40. Storage of Flammable Liquids in Containers, HS(G)51 Storage of Packaged Dangerous Substances, HS(G)71EU LegislationDangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments. Classification, labelling and packaging of substances and mixtures 1272/2008ECNational RegulationsThe Control Of Substances Hazardous to Health regulations (as amended) The Manual Handling Operations regulations (as amended) The Environmental Protection (Duty of Care) regulations (as amended) The Chemicals (Hazard Information and Packaging) for supply regulations (as amended) The Health and Safety at Work act 1974 (as amended) No chemical safety assessment has been carried out.
General informationThe information contained in this safety data sheet is provided in accordance with the requirements of the regulations. The product should not be used for purposes other than those shown in section 1 without first referring to the supplier and obtaining written handling instruction. As the specific conditions of use of the product are outside the suppliers control, the user is responsible for ensuring that the requirements of relevant legislation are complied with.
Revision CommentsThis information is provided in a revised format to that previously produced.
Issued By Harmful by inhalation and if swallowed.
Harmful: may cause lung damage if swallowed.
May cause sensitisation by skin contact.
Repeated exposure may cause skin dryness or cracking.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Vapours may cause drowsiness and dizziness.
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Repeated exposure may cause skin dryness or cracking.
May be fatal if swallowed and enters airways.
May cause an allergic skin reaction.
Very toxic to aquatic life with long lasting effects.
The information provided in this safety data sheet is based on the present state of knowledge and current national legislation. It provides guidance on health and safety and environmental aspects and should not be construed as any guarantee of technical performance or suitablility for particular applications.

Source: http://www.crowntrade.co.uk/Safety%20Data%20Sheets/woodcareallpurposepreserver.pdf