Safety data sheet
according to 1907/2006/EC, Article 31
1 Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Article number: 022-C
· Registration number Not applicable
· Application of the substance / the preparation Dental bonding material
· Details of the supplier of the safety data sheet
· Manufacturer:
Kuraray Europe GmbHPhilipp-Reis-Str. 4,65795 Hattersheim am MainGermanyPhone:+49 (0)69 305 35 840Fax:+49 (0)69 305 35 640E-mail: · Supplier:
J & S DavisUnit 6, Argyle Way Trading Estate,Fulton Close, Stevenage,Hertfordshire, SG 1 2AF,Great BritainTel: +44- (0)1438 735800Fax: +44- (0)1438 735801E-mail: · Further information obtainable from: Manufacturer or Supplier
· Emergency telephone number:
National Poisons information Service (London Centre)Guy’s & St. Thomas’ Hospital TrustMedical Toxicology UnitAvonley RoadLONDONSE14 5EREmergency telephone: (local) 0870 600 6266 or +44 20 7771 5394Administrative telephone: +44 20 7 771 53 10Facsimile number: +44 20 7 771 53 09 2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
Skin Irrit. 2 H315 Causes skin irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R36/38: Irritating to eyes and skin.
May cause sensitisation by skin contact.
· Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline forpreparations of the EU" in the latest valid version.
Safety data sheet
according to 1907/2006/EC, Article 31
· Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literaturedata.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms GHS07
· Signal word Warning
· Hazard-determining components of labelling:
2-hydroxyethyl methacrylatebenzoyl peroxide · Hazard statements
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
· Precautionary statements
Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Specific treatment (see on this label).
Take off contaminated clothing and wash before reuse.
If skin irritation occurs: Get medical advice/attention.
· Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components:
Xi R36/38 Skin Irrit. 2, H315; Eye Irrit. 2, H319 Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317 · Other ingredients:
10-Methacryloyloxydecyl dihydrogen phosphateHydrophobic aliphatic methacrylateOthers 4 First aid measures
· Description of first aid measures
· After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
Safety data sheet
according to 1907/2006/EC, Article 31
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Do not induce vomiting; call for medical help immediately.
If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
· Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
· Handling:
· Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about fire - and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store in a refrigerator (2-8°C).
· Information about storage in one common storage facility:
Store away from oxidizing agents.
Store away from reducing agents.
· Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
· Specific end use(s) No further relevant information available.
Safety data sheet
according to 1907/2006/EC, Article 31
8 Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.
· Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures:
Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
· Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective device.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation · Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to beobserved.
· Eye protection:
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
· Odour:
· pH-value:
· Change in condition
Melting point/Melting range:
Safety data sheet
according to 1907/2006/EC, Article 31
Boiling point/Boiling range:
· Flash point:
· Ignition temperature:
· Danger of explosion:
Product does not present an explosion hazard.
· Explosion limits:
· Vapour pressure:
· Density:
· Vapour density
· Solubility in / Miscibility with
· Segregation coefficient (n-octanol/water): Not applicable
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials: No further relevant information available.
· Hazardous decomposition products: Carbon monoxide and carbon dioxide
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
868-77-9 2-hydroxyethyl methacrylate
94-36-0 benzoyl peroxide
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritating effect.
· Sensitization: Sensitization possible through skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version: Safety data sheet
according to 1907/2006/EC, Article 31
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for waterDo not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
14 Transport information
· UN-Number
· UN proper shipping name
· Transport hazard class(es)
· Class
· Packing group
· Environmental hazards:
· Marine pollutant:
· Special precautions for user
· Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
· UN "Model Regulation":
Safety data sheet
according to 1907/2006/EC, Article 31
15 Regulatory information
· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.
· Version: 5
· Relevant phrases
Heating may cause a fire or explosion.
May cause an allergic skin reaction.
Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R36/38 Irritating to eyes and skin.
R43 May cause sensitisation by skin contact.


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