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Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
Product information
Alfred-Nobel-Straße 50 40789 Monheim Germany Telephone +49(0)69-305-5748 Telefax +49(0)69-305-80950 Responsible Department Material and Transport Safety Management +49(0)69-305-82369/12588 Emergency telephone number +49(0)2133-51-4233 (Sicherheitszentrale Dormagen, Bayer AG) 2. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical nature
Hazardous components
3. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Harmful by inhalation. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 4. FIRST AID MEASURES
General advice
Move out of dangerous area. If the patient is likely to become unconscious, place and transport in stable sideways position. Remove soiled or soaked clothing immediately. Also heed the risks to your own person. Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
Inhalation
Move the patient to fresh air and keep at rest. Call a physician immediately.
Skin contact
Wash off immediately with soap and plenty of water. Call a physician immediately.
Eye contact
In case of contact with eyes rinse thoroughly with water. Cal a physician immediately.
Ingestion
Do not induce vomiting. Wash out mouth with water. Call a physician immediately.
Notes to physician

Treatment
Treat symptomatically. Gastric lavage, then charcoal (carbo medicalis) and sodium sulfate. Follow-up measures: Strict abstinence from alcohol for 1 - 2 weeks, due to Antabuse effect. 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media
water spray carbon dioxide (CO2) foam sand Specific hazards during fire fighting
In the event of fire the following can be released: hydrogen cyanide (hydrocyanic acid) carbon monoxide (CO) sulphur dioxide (SO2) nitrogen oxides (NOx) Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes. Use breathing apparatus. Further information
Contain the spread of the fire-fighting media. Do not allow run-off from fire fighting to enter drains or water courses. 6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Avoid contact with spilled product or contaminated surfaces. Wear personal protective equipment. Unprotected persons must be kept away. Keep away sources of ignition. Environmental precautions
Do not discharge into the drains/surface water/groundwater. Methods for cleaning up
Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations Pack spilled material in suitable containers for recovery or disposal. Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
Additional advice
Information regarding personal protective equipment, see section 8. Information regarding waste disposal, see section 13. 7. HANDLING AND STORAGE
Handling

Advice on safe handling
Use only in area provided with appropriate exhaust ventilation. Advice on protection against fire and explosion Keep away from heat and sources of ignition. Dust explosivity : sensitive Requirements for storage areas and containers Keep containers tightly closed in a dry, cool and well-ventilated place. Store in original container. Store in a place accessible by authorized persons only. Keep away from food, drink and animal feedingstuffs. Only use containers that are approved specifically for the substance/ product. LDPE (low density polyethylene) 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protective equipment
If product is handled while not enclosed, and if skin contact may occur: Dust mask Avoid contact with skin, eyes and clothing. Keep working clothes separately. Wash hands immediately after work, if necessary take a shower Remove soiled or soaked clothing immediately and clean thoroughly before using again. Garments that cannot be cleaned must be destroyed (burnt). If product is handled while not enclosed, and if skin contact may occur: complete suit protecting against chemicals Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Safety data
capable of causing a dust explosion (modified Hartmann tube, ignition with continuous spark generator) 10. STABILITY AND REACTIVITY
With acids carbon disulphide and hydrogen sulphide may evolve. 11. TOXICOLOGICAL INFORMATION
LC50 (rat) ca. 5,040 mg/l Tested in the form of respirable fine dust. sensitizing (guinea pig) OECD Test Guideline 406, Magnusson & Kligman test 12. ECOLOGICAL INFORMATION
Ecotoxicity effects
LC50 (Rainbow trout (Oncorhynchus mykiss)) 6,7 mg/l Exposure time: 96 h EC50 (Water flea (Daphnia magna)) 4,7 mg/l Exposure time: 48 h The value mentioned relates to the active ingredient propineb. Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
EC50 (Desmodesmus subspicatus) 2,68 mg/l Growth rate Exposure time: 96 h The value mentioned relates to the active ingredient propineb. 13. DISPOSAL CONSIDERATIONS
Dispose of by incineration in an authorised special waste incineration plant. Comply with local legislation. For larger quantities contact manufacturer.
Waste key for the unused product
020108 agrochemical waste containing dangerous substances 14. TRANSPORT INFORMATION
ADR/RID/ADNR
UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. 15. REGULATORY INFORMATION
Classification and labelling in accordance with the EC Directive on dangerous preparations 1999/45/EC as amended. Classification: Hazardous components which must be listed on the label: Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. This material and its container must be disposed of in a safe way. Use appropriate containment to avoid environmental contamination. To avoid risks to man and the environment, comply with the instructions for use. WHO-classification: III (Slightly hazardous) National legislation
Subjected to the "Disasters and Major Accidents Act " involving dangerous substances Other regulations BG Leaflet M050 "Handling of Hazardous Substances" BG Leaflet M053 "General Protective Measures for the Handling of Hazardous Substances" 16. OTHER INFORMATION
Further information
Text of R phrases mentioned in Section 2: May cause sensitization by inhalation and skin contact. May cause sensitization by skin contact. Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. The information given in this Data Sheet has been included in accordance with the guidelines established by EC Directive 1991/155/EC as amended. This data sheet complements the user's instructions, but does not replace them. The information it contains is based on the knowledge available about the product concerned at the time it was compiled. Users are further reminded of the possible risks of using a product for purposes other than those for which it was intended. The required information complies with current EEC legislation. Addressees are requested to observe Bayer CropScience SAFETY DATA SHEET according to EC Directive 2001/58/EC
PROPINEB WP 70R W U-WW
any additional national requirements. This information is based on our present state of knowledge. It should not therefore be construed as guaranteeing specific properties of the products described or their suitability for a particular application. For further information on active ingredients see also: Wirkstoffe in Pflanzenschutz- und Schädlingsbekämpfungsmitteln: physikalisch-chemische und toxikologische Daten IVA, Industrieverb. Agrar e.V. - 3., neubearb. Aufl. - München; Wien; Zürich; BLV Verl.-Ges.mbH, 2000 ISBN 3-405-15809-5 Changes since the last version will be highlighted in the margin. This version replaces all previous versions.

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